"Presider over weddings in Greek myth" NYT crossword answer is:HERA (4 letters length)
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In Greek mythology, a presider over weddings was known as a Hymenaios, who was the god of marriage and weddings. He was often depicted as a young man with a torch and a veil, and was believed to bring luck and blessings to the newlyweds. He was also said to bring music and joy to the wedding ceremony, and was seen as a symbol of fertility and prosperity.